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Well-Defined Nanographene–Rhenium Complex as an Efficient Electrocatalyst and Photocatalyst for Selective CO2 Reduction

zhpd55 添加于 2017/3/12 17:01:38  305次阅读 | 0次推荐 | 0个评论

Improving energy efficiency of electrocatalytic and photocatalytic CO2 conversion to useful chemicals poses a significant scientific challenge. We report on using a colloidal nanographene to form a molecular complex with a metal ion to tackle this challenge. In this work, a well-defined nanographene–Re complex was synthesized, in which electron delocalization over the nanographene and the metal ion significantly decreases the electrical potential needed to drive the chemical reduction. We show the complex can selectively electrocatalyze CO2 reduction to CO in tetrahydrofuran at −0.48 V vs NHE, the least negative potential reported for a molecular catalyst. In addition, the complex can absorb a significant spectrum of visible light to photocatalyze the chemical transformation without the need for a photosensitizer.

作 者:Xiaoxiao Qiao, Qiqi Li, Richard N. Schaugaard, Benjamin W. Noffke, Yijun Liu , Dongping Li, Lu Liu, Krishnan Raghavachari , and Liang-shi Li
期刊名称: J. Am. Chem. Soc.
期卷页: Publication Date (Web): March 8, 2017 第卷 第期 页
学科领域:化学科学 » 无机化学 » 无机纳米化学
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原文链接:http://pubs.acs.org/doi/abs/10.1021/jacs.6b12530
DOI: 10.1021/jacs.6b12530
ISBN:
关键词: Nanographene−Rhenium Complex, Electrocatalyst, Photocatalyst, CO2 Reduction
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备 注: An international team of scientists led by Liang-shi Li at Indiana University has achieved a new milestone in the quest to recycle carbon dioxide in the Earth's atmosphere into carbon-neutral fuels and others materials. The chemists have engineered a molecule that uses light or electricity to convert the greenhouse gas carbon dioxide into carbon monoxide—a carbon-neutral fuel source—more efficiently than any other method of "carbon reduction." The process is reported today in the Journal of the American Chemical Society. "If you can create an efficient enough molecule for this reaction, it will produce energy that is free and storable in the form of fuels," said Li, associate professor in the IU Bloomington College of Arts and Sciences' Department of Chemistry. "This study is a major leap in that direction." Burning fuel—such as carbon monoxide—produces carbon dioxide and releases energy. Turning carbon dioxide back into fuel requires at least the same amount of energy. A major goal among scientists has been decreasing the excess energy needed.
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